Please use this identifier to cite or link to this item: https://doi.org/10.1039/c7cc04554a
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dc.titleStrong ferromagnetic exchange coupling in a {Ni-4(II)} cluster mediated through an air-stable tetrazine-based radical anion
dc.contributor.authorLemes, Maykon A
dc.contributor.authorBrunet, Gabriel
dc.contributor.authorPialat, Amelie
dc.contributor.authorUngur, Liviu
dc.contributor.authorKorobkov, Ilia
dc.contributor.authorMurugesu, Muralee
dc.date.accessioned2022-07-15T08:12:28Z
dc.date.available2022-07-15T08:12:28Z
dc.date.issued2017-08-11
dc.identifier.citationLemes, Maykon A, Brunet, Gabriel, Pialat, Amelie, Ungur, Liviu, Korobkov, Ilia, Murugesu, Muralee (2017-08-11). Strong ferromagnetic exchange coupling in a {Ni-4(II)} cluster mediated through an air-stable tetrazine-based radical anion. CHEMICAL COMMUNICATIONS 53 (62) : 8660-8663. ScholarBank@NUS Repository. https://doi.org/10.1039/c7cc04554a
dc.identifier.issn13597345
dc.identifier.issn1364548X
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228686
dc.description.abstractA planar tetradentate 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine (BpymTz) templating chelate affords the formation of an unprecedented BpymTz- radical anion bridged {NiII4} complex. Detailed magnetic measurements performed on the isolated air stable [NiII4(BpymTz-)Cl6(DMF)8]Cl·0.5(H2O) compound reveal strong ferromagnetic NiII-BpymTz- interactions with a coupling constant of J = 98.84 cm-1.
dc.language.isoen
dc.publisherROYAL SOC CHEMISTRY
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectNICKEL(II) COMPLEXES
dc.subject1,4-DIHYDRO FORM
dc.subjectDONOR LIGANDS
dc.subjectSPIN
dc.subjectSTATES
dc.subjectDINUCLEAR
dc.subjectNITROXIDE
dc.subjectMAGNETISM
dc.subjectRU
dc.typeArticle
dc.date.updated2022-07-15T02:50:25Z
dc.contributor.departmentDEPT OF CHEMISTRY
dc.description.doi10.1039/c7cc04554a
dc.description.sourcetitleCHEMICAL COMMUNICATIONS
dc.description.volume53
dc.description.issue62
dc.description.page8660-8663
dc.published.statePublished
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