Please use this identifier to cite or link to this item:
https://doi.org/10.1039/c5cc10072k
| Title: | Porosity in metal-organic framework glasses | Authors: | Thornton, A.W Jelfs, K.E Konstas, K Doherty, C.M Hill, A.J Cheetham, A.K Bennett, T.D |
Issue Date: | 2016 | Publisher: | Royal Society of Chemistry | Citation: | Thornton, A.W, Jelfs, K.E, Konstas, K, Doherty, C.M, Hill, A.J, Cheetham, A.K, Bennett, T.D (2016). Porosity in metal-organic framework glasses. Chemical Communications 52 (19) : 3750-3753. ScholarBank@NUS Repository. https://doi.org/10.1039/c5cc10072k | Rights: | Attribution 4.0 International | Abstract: | The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses. © The Royal Society of Chemistry 2016. | Source Title: | Chemical Communications | URI: | https://scholarbank.nus.edu.sg/handle/10635/179621 | ISSN: | 1359-7345 | DOI: | 10.1039/c5cc10072k | Rights: | Attribution 4.0 International |
| Appears in Collections: | Staff Publications Elements |
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| 10_1039_c5cc10072k.pdf | 2.97 MB | Adobe PDF | OPEN | None | View/Download |
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