Please use this identifier to cite or link to this item: https://doi.org/10.1039/c5cc10072k
Title: Porosity in metal-organic framework glasses
Authors: Thornton, A.W
Jelfs, K.E
Konstas, K
Doherty, C.M
Hill, A.J
Cheetham, A.K 
Bennett, T.D
Issue Date: 2016
Publisher: Royal Society of Chemistry
Citation: Thornton, A.W, Jelfs, K.E, Konstas, K, Doherty, C.M, Hill, A.J, Cheetham, A.K, Bennett, T.D (2016). Porosity in metal-organic framework glasses. Chemical Communications 52 (19) : 3750-3753. ScholarBank@NUS Repository. https://doi.org/10.1039/c5cc10072k
Rights: Attribution 4.0 International
Abstract: The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses. © The Royal Society of Chemistry 2016.
Source Title: Chemical Communications
URI: https://scholarbank.nus.edu.sg/handle/10635/179621
ISSN: 1359-7345
DOI: 10.1039/c5cc10072k
Rights: Attribution 4.0 International
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