Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/17534
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dc.titleSurface-supported transition metal hexacyanometallate nanostructured films
dc.contributor.authorNAGAMOOTTOO LORNA
dc.date.accessioned2010-07-13T18:00:25Z
dc.date.available2010-07-13T18:00:25Z
dc.date.issued2007-01-12
dc.identifier.citationNAGAMOOTTOO LORNA (2007-01-12). Surface-supported transition metal hexacyanometallate nanostructured films. ScholarBank@NUS Repository.
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/17534
dc.description.abstractIn this thesis, analogues of Prussian Blue belonging to a family of hexacyanometallates, were synthesized and deposited as thin films on various supports using the method of Electrostatic Self-Assembly (ESA). The thickness, morphology and electrochemical behaviour of the films were analysed by various techniques such as IR Spectroscopy, Visble-UV spectroscopy, AFM, SEM, XPS, X-ray Reflectivity and Cyclic Voltammetry. It was shown that Ruthenium(III) Hexacyanoferrate(II) could be obtained regardless of whether the ferrate(II) or the ferrate(III) was used in the starting reagents. Futhermore, the effects of linkage isomerism were observed in Iron(III) Hexacyanochromate and Ruthenium(III) Hexacyanochromate. When the cyclic voltammetry of the ruthenium films was done, the voltammograms showed reversible couples for all the films. It was also demonstrated that this family of cyano-complexes could be directly deposited on various supports by the ESA method. Turnbulla??s Blue and Copper(II) Hexacyanoferrate(II) multilayers were successfully deposited on gold.
dc.language.isoen
dc.subjectPrussian Blue Analogues, Thin Films, Electrostatic Self-Assembly
dc.typeThesis
dc.contributor.departmentCHEMISTRY
dc.contributor.supervisorSIM WEE SUN
dc.description.degreeMaster's
dc.description.degreeconferredMASTER OF SCIENCE
dc.identifier.isiutNOT_IN_WOS
Appears in Collections:Master's Theses (Open)

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