Please use this identifier to cite or link to this item: https://doi.org/10.1039/c7cc02743e
Title: Breathing-induced new phase transition in an MIL-53(Al)-NH2 metal-organic framework under high methane pressures
Authors: Bolinois, Linius
Kundu, Tanay 
Wang, Xuerui 
Wang, Yuxiang 
Hu, Zhigang 
Koh, Kenny
Zhao, Dan 
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
NATURAL-GAS
POROUS MATERIALS
CO2 ADSORPTION
STORAGE
MIL-53
SEPARATION
BEHAVIOR
FUNCTIONALIZATION
SORPTION
Issue Date: 25-Jul-2017
Publisher: ROYAL SOC CHEMISTRY
Citation: Bolinois, Linius, Kundu, Tanay, Wang, Xuerui, Wang, Yuxiang, Hu, Zhigang, Koh, Kenny, Zhao, Dan (2017-07-25). Breathing-induced new phase transition in an MIL-53(Al)-NH2 metal-organic framework under high methane pressures. CHEMICAL COMMUNICATIONS 53 (58) : 8118-8121. ScholarBank@NUS Repository. https://doi.org/10.1039/c7cc02743e
Abstract: © 2017 The Royal Society of Chemistry. The high pressure methane sorption tests on a flexible metal-organic framework [MIL-53(Al)-NH2] reveal a new phase transition to a large pore (lp) phase above 45 bar. The mixed-ligand strategy and pressure cycling tests are suggested to reduce the pressure requirement of such a phase transition for applications in natural gas storage
Source Title: CHEMICAL COMMUNICATIONS
URI: https://scholarbank.nus.edu.sg/handle/10635/170208
ISSN: 13597345
1364548X
DOI: 10.1039/c7cc02743e
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