Please use this identifier to cite or link to this item: https://doi.org/10.1021/acssuschemeng.8b05463
Title: Scalable and Sustainable Synthesis of Advanced Porous Materials
Authors: Peh, Shing Bo 
Wang, Yuxiang 
Zhao, Dan 
Keywords: Science & Technology
Physical Sciences
Technology
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Engineering, Chemical
Chemistry
Science & Technology - Other Topics
Engineering
Porous materials
Scale-up production
Green synthesis
Continuous processing
METAL-ORGANIC FRAMEWORKS
CONJUGATED MICROPOROUS POLYMER
HIGH-SURFACE-AREA
MECHANOCHEMICAL MILLING REACTIONS
ASSISTED SOLVOTHERMAL SYNTHESIS
TRIAZINE-BASED FRAMEWORKS
CONTINUOUS-FLOW SYNTHESIS
GEL CONVERSION SYNTHESIS
SOLVENT-FREE SYNTHESIS
IN-SITU
Issue Date: 18-Feb-2019
Publisher: AMERICAN CHEMICAL SOCIETY
Citation: Peh, Shing Bo, Wang, Yuxiang, Zhao, Dan (2019-02-18). Scalable and Sustainable Synthesis of Advanced Porous Materials. ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7 (4) : 3647-3670. ScholarBank@NUS Repository. https://doi.org/10.1021/acssuschemeng.8b05463
Abstract: © 2019 American Chemical Society. Advanced porous materials (APMs) constructed from structure-encoded building blocks present an unprecedented degree for molecular design, and have demonstrated class-leading performance in numerous applications. However, the development of economically viable and sustainable synthetic means of production is a critical prerequisite to translate APMs to real-world applications. In this Perspective, we first consider the diverse synthetic routes to APMs - metal/covalent organic frameworks (MOFs/COFs), porous organic polymers (POPs) and porous molecular solids - and highlight the challenges for scalable and sustainable synthesis. Subsequently, we illustrate concepts to guide the sustainable synthesis of APMs with recent examples in the literature. Lastly, we present our outlook for the translation of molecular design to scalable APM production.
Source Title: ACS SUSTAINABLE CHEMISTRY & ENGINEERING
URI: https://scholarbank.nus.edu.sg/handle/10635/169832
ISSN: 21680485
DOI: 10.1021/acssuschemeng.8b05463
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