Please use this identifier to cite or link to this item: https://doi.org/10.1021/acs.chemmater.8b05332
Title: Functionalization-Induced Breathing Control in Metal-Organic Frameworks for Methane Storage with High Deliverable Capacity
Authors: Kundu, Tanay 
Shah, Bhuvan B
Bolinois, Linius
Zhao, Dan 
Keywords: Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Materials Science, Multidisciplinary
Chemistry
Materials Science
NATURAL-GAS STORAGE
HIGH-PRESSURE
ADSORPTION
BINDING
Issue Date: 23-Apr-2019
Publisher: AMERICAN CHEMICAL SOCIETY
Citation: Kundu, Tanay, Shah, Bhuvan B, Bolinois, Linius, Zhao, Dan (2019-04-23). Functionalization-Induced Breathing Control in Metal-Organic Frameworks for Methane Storage with High Deliverable Capacity. CHEMISTRY OF MATERIALS 31 (8) : 2842-2847. ScholarBank@NUS Repository. https://doi.org/10.1021/acs.chemmater.8b05332
Abstract: © 2019 American Chemical Society. Metal-organic frameworks (MOFs) that can undergo structural flexibility upon gas sorption cycle bear enormous potential particularly as adsorbents for methane storage. A molecular level control over such flexibility can be advantageous for the development of smart adsorbents with increased deliverable capacity. Herein, we report the flexible and stable MIL-53(Al) type MOFs, whose breathing behavior can be controlled by systematic installation of hydrogen bonding sites into the frameworks. Such a control has been fine-tuned to induce high deliverable capacity in MOFs by changing gas pressure, temperature, and density. The establishment of a structure-property relationship for methane storage and successful pelletization of MOFs pave the way for MOF-based onboard natural gas storage.
Source Title: CHEMISTRY OF MATERIALS
URI: https://scholarbank.nus.edu.sg/handle/10635/169751
ISSN: 08974756
15205002
DOI: 10.1021/acs.chemmater.8b05332
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