Please use this identifier to cite or link to this item:
https://doi.org/10.1002/cctc.201901167
DC Field | Value | |
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dc.title | Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates | |
dc.contributor.author | Sun, Qiming | |
dc.contributor.author | Fu, Xinpu | |
dc.contributor.author | Si, Rui | |
dc.contributor.author | Wang, Chi-Hwa | |
dc.contributor.author | Yan, Ning | |
dc.date.accessioned | 2020-06-02T01:14:25Z | |
dc.date.available | 2020-06-02T01:14:25Z | |
dc.date.issued | 2019-09-24 | |
dc.identifier.citation | Sun, Qiming, Fu, Xinpu, Si, Rui, Wang, Chi-Hwa, Yan, Ning (2019-09-24). Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates. CHEMCATCHEM 11 (20) : 5093-5097. ScholarBank@NUS Repository. https://doi.org/10.1002/cctc.201901167 | |
dc.identifier.issn | 18673880 | |
dc.identifier.issn | 18673899 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/168917 | |
dc.description.abstract | © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim CO2 hydrogenation to formic acid/formate has been recognized as a key reaction to realizing the CO2-mediated hydrogen energy cycle. Herein, ultrafine and well-dispersed Pd−CoO nanoparticles (∼1.8 nm) were encapsulated within mesoporous silica nanospheres (MSNs) via a facile one-pot ligand-protected synthesis strategy. The MSN-encaged bimetallic nanocatalysts exhibit excellent catalytic activity and stability for the formate production from CO2 hydrogenation, showing high turnover frequency value up to 1824 h−1 at 373 K, which is among the top-level reported for heterogeneous catalysts. | |
dc.language.iso | en | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.source | Elements | |
dc.subject | Heterogeneous catalysis | |
dc.subject | CO2 hydrogenation | |
dc.subject | Formates | |
dc.subject | Mesoporous silica | |
dc.subject | Nanocatalysts | |
dc.type | Article | |
dc.date.updated | 2020-05-30T17:44:57Z | |
dc.contributor.department | CHEMICAL & BIOMOLECULAR ENGINEERING | |
dc.description.doi | 10.1002/cctc.201901167 | |
dc.description.sourcetitle | CHEMCATCHEM | |
dc.description.volume | 11 | |
dc.description.issue | 20 | |
dc.description.page | 5093-5097 | |
dc.published.state | Published | |
Appears in Collections: | Staff Publications Staff Publications Elements |
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chemcatchem-revised-20190809-unmarked.docx | Accepted version | 7.76 MB | Microsoft Word XML | OPEN | Post-print | View/Download |
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