Please use this identifier to cite or link to this item:
https://doi.org/10.1002/cctc.201901167
Title: | Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates | Authors: | Sun, Qiming Fu, Xinpu Si, Rui Wang, Chi-Hwa Yan, Ning |
Keywords: | Heterogeneous catalysis CO2 hydrogenation Formates Mesoporous silica Nanocatalysts |
Issue Date: | 24-Sep-2019 | Publisher: | WILEY-V C H VERLAG GMBH | Citation: | Sun, Qiming, Fu, Xinpu, Si, Rui, Wang, Chi-Hwa, Yan, Ning (2019-09-24). Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates. CHEMCATCHEM 11 (20) : 5093-5097. ScholarBank@NUS Repository. https://doi.org/10.1002/cctc.201901167 | Abstract: | © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim CO2 hydrogenation to formic acid/formate has been recognized as a key reaction to realizing the CO2-mediated hydrogen energy cycle. Herein, ultrafine and well-dispersed Pd−CoO nanoparticles (∼1.8 nm) were encapsulated within mesoporous silica nanospheres (MSNs) via a facile one-pot ligand-protected synthesis strategy. The MSN-encaged bimetallic nanocatalysts exhibit excellent catalytic activity and stability for the formate production from CO2 hydrogenation, showing high turnover frequency value up to 1824 h−1 at 373 K, which is among the top-level reported for heterogeneous catalysts. | Source Title: | CHEMCATCHEM | URI: | https://scholarbank.nus.edu.sg/handle/10635/168917 | ISSN: | 18673880 18673899 |
DOI: | 10.1002/cctc.201901167 |
Appears in Collections: | Staff Publications Staff Publications Elements |
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chemcatchem-revised-20190809-unmarked.docx | Accepted version | 7.76 MB | Microsoft Word XML | OPEN | Post-print | View/Download |
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