Please use this identifier to cite or link to this item:
https://doi.org/10.1021/acs.orglett.6b01196
DC Field | Value | |
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dc.title | Kinetically Blocked Stable 5,6:12,13-Dibenzozethrene: A Laterally pi-Extended Zethrene with Enhanced Diradical Character | |
dc.contributor.author | Yadav, Priya | |
dc.contributor.author | Das, Soumyajit | |
dc.contributor.author | Phan, Hoa | |
dc.contributor.author | Herng, Tun Seng | |
dc.contributor.author | Ding, Jun | |
dc.contributor.author | Wu, Jishan | |
dc.date.accessioned | 2020-05-04T09:36:26Z | |
dc.date.available | 2020-05-04T09:36:26Z | |
dc.date.issued | 2016-06-17 | |
dc.identifier.citation | Yadav, Priya, Das, Soumyajit, Phan, Hoa, Herng, Tun Seng, Ding, Jun, Wu, Jishan (2016-06-17). Kinetically Blocked Stable 5,6:12,13-Dibenzozethrene: A Laterally pi-Extended Zethrene with Enhanced Diradical Character. ORGANIC LETTERS 18 (12) : 2886-2889. ScholarBank@NUS Repository. https://doi.org/10.1021/acs.orglett.6b01196 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.issn | 1523-7052 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/167650 | |
dc.description.abstract | © 2016 American Chemical Society. Although the ground-state and physical properties of zethrene and recently invented 1,2:8,9-dibenzozethrene have been well studied, the other dibenzozethrene isomer, i.e., 5,6:12,13-dibenzozethrene, remained unexplored. A short synthetic route to a kinetically blocked stable 5,6:12,13-dibenzozethrene derivative 5 is presented. The ground state is found to be open-shell singlet experimentally, and the theoretical y0 was enhanced to 0.414, which corroborates nicely with the experimental and theoretical singlet-triplet energy gap. | |
dc.language.iso | en | |
dc.publisher | AMER CHEMICAL SOC | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Organic | |
dc.subject | Chemistry | |
dc.subject | OPEN-SHELL | |
dc.subject | GROUND-STATES | |
dc.subject | CLOSED-SHELL | |
dc.subject | FUSION MODE | |
dc.subject | HYDROCARBON | |
dc.subject | PERYLENE)QUINODIMETHANES | |
dc.subject | QUINODIMETHANES | |
dc.subject | OCTAZETHRENE | |
dc.subject | REACTIVITY | |
dc.subject | MOLECULES | |
dc.type | Article | |
dc.date.updated | 2020-05-04T06:30:51Z | |
dc.contributor.department | DEPT OF CHEMISTRY | |
dc.contributor.department | DEPT OF MATERIALS SCIENCE & ENGINEERING | |
dc.description.doi | 10.1021/acs.orglett.6b01196 | |
dc.description.sourcetitle | ORGANIC LETTERS | |
dc.description.volume | 18 | |
dc.description.issue | 12 | |
dc.description.page | 2886-2889 | |
dc.published.state | Published | |
Appears in Collections: | Staff Publications Elements |
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TIPS-DBZ.pdf | Published version | 1.19 MB | Adobe PDF | CLOSED | None |
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