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https://doi.org/10.1107/S2414314616019829
Title: | t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one oxime | Authors: | RAMALINGAM ARULRAJ S. Sivakumar A. Thiruvalluvar A. Manimekalai |
Keywords: | Crystal structure piperidin-4-oneoxime O—H⋯N hydrogen bonding C—H⋯π interactions |
Issue Date: | 12-Dec-2016 | Publisher: | International Union of Crystallography | Citation: | RAMALINGAM ARULRAJ, S. Sivakumar, A. Thiruvalluvar, A. Manimekalai (2016-12-12). t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one oxime. IUCrData 1 (12) : 1-9. ScholarBank@NUS Repository. https://doi.org/10.1107/S2414314616019829 | Abstract: | In the title compound, C24H24N2O [systematic name: (E)-3-benzyl-2,6-diphenylpiperidin-4-one oxime], the piperidine ring adopts a slightly distorted chair conformation and the phenyl rings and the benzyl group substituents are attached equatorially. The oxime group makes a dihedral angle of 42.88 (12)° with the piperidine ring. The dihedral angle between the phenyl rings is 71.96 (8)°. The benzyl ring makes dihedral angles of 63.01 (8) and 59.35 (8)° with the two phenyl rings. In the crystal, molecules are linked by O—H⋯N hydrogen bonds, forming C(7) chains along the c axis. The chains are linked by C—H⋯π interactions, forming slabs lying parallel to the bc plane. | Source Title: | IUCrData | URI: | https://scholarbank.nus.edu.sg/handle/10635/165298 | ISSN: | 2414-3146 | DOI: | 10.1107/S2414314616019829 |
Appears in Collections: | Staff Publications Elements |
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