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Title: t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one oxime
S. Sivakumar
A. Thiruvalluvar
A. Manimekalai
Keywords: Crystal structure
O—H⋯N hydrogen bonding
C—H⋯π inter­actions
Issue Date: 12-Dec-2016
Publisher: International Union of Crystallography
Citation: RAMALINGAM ARULRAJ, S. Sivakumar, A. Thiruvalluvar, A. Manimekalai (2016-12-12). t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one oxime. IUCrData 1 (12) : 1-9. ScholarBank@NUS Repository.
Abstract: In the title compound, C24H24N2O [systematic name: (E)-3-benzyl-2,6-di­phenyl­piperidin-4-one oxime], the piperidine ring adopts a slightly distorted chair conformation and the phenyl rings and the benzyl group substituents are attached equatorially. The oxime group makes a dihedral angle of 42.88 (12)° with the piperidine ring. The dihedral angle between the phenyl rings is 71.96 (8)°. The benzyl ring makes dihedral angles of 63.01 (8) and 59.35 (8)° with the two phenyl rings. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds, forming C(7) chains along the c axis. The chains are linked by C—H⋯π inter­actions, forming slabs lying parallel to the bc plane.
Source Title: IUCrData
ISSN: 2414-3146
DOI: 10.1107/S2414314616019829
Appears in Collections:Staff Publications

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