Please use this identifier to cite or link to this item: https://doi.org/10.1107/S2056989016020661
Title: Crystal structures of three 3-chloro-3-methyl-2,6-diarylpiperidin-4-ones
Authors: RAMALINGAM ARULRAJ 
S. Sivakumar
Manpreet Kaur
A. Thiruvalluvar
Jerry P. Jasinski
Keywords: Crystal structures
3-chloro-3-methyl- 2,6-diphenyl-piperidin-4-ones
Hydrogen bonds
C—H⋯π inter­actions
Issue Date: 29-Dec-2016
Publisher: International Union of Crystallography
Citation: RAMALINGAM ARULRAJ, S. Sivakumar, Manpreet Kaur, A. Thiruvalluvar, Jerry P. Jasinski (2016-12-29). Crystal structures of three 3-chloro-3-methyl-2,6-diarylpiperidin-4-ones. Acta Crystallographica Section E: Crystallographic Communications 73 (2) : 107-111. ScholarBank@NUS Repository. https://doi.org/10.1107/S2056989016020661
Abstract: The syntheses and crystal structure of 3-chloro-3-methyl-r-2,c-6-di­phenyl­piperidin-4-one, C18H18ClNO, (I), 3-chloro-3-methyl-r-2,c-6-di-p-tolyl­piperidin-4-one, C20H22ClNO, (II), and 3-chloro-3-methyl-r-2,c-6-bis­(4-chloro­phen­yl)piperidin-4-one, C18H16Cl3NO, (III), are described. In each structure, the piperidine ring adopts a chair conformation and dihedral angles between the mean planes of the phenyl rings are 58.4 (2), 73.5 (5) and 78.6 (2)° in (I), (II) and (III), respectively. In the crystals, mol­ecules are linked into C(6) chains by weak N—H⋯O hydrogen bonds and C—H⋯π inter­actions are also observed
Source Title: Acta Crystallographica Section E: Crystallographic Communications
URI: https://scholarbank.nus.edu.sg/handle/10635/165297
ISSN: 2056-9890
DOI: 10.1107/S2056989016020661
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