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https://scholarbank.nus.edu.sg/handle/10635/164569
DC Field | Value | |
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dc.title | REDOX FLOW BATTERY FOR LARGE-SCALE ENERGY STORAGE | |
dc.contributor.author | ZHOU MINGYUE | |
dc.date.accessioned | 2020-02-13T18:00:34Z | |
dc.date.available | 2020-02-13T18:00:34Z | |
dc.date.issued | 2019-08-23 | |
dc.identifier.citation | ZHOU MINGYUE (2019-08-23). REDOX FLOW BATTERY FOR LARGE-SCALE ENERGY STORAGE. ScholarBank@NUS Repository. | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/164569 | |
dc.description.abstract | Redox-targeting reactions incorporate solid material with the redox flow battery (RFB) system to increase energy density and open new areas for RFBs. However, the first generation of redox-targeting based RFBs suffers from low voltage efficiency, low power capability, and high cost. In this thesis, efforts were made to develop the second generation of redox-targeting based RFBs in order to solve those limitations. A new reaction mechanism called Single-Molecule Redox-Targeting (SMRT) reaction was proposed and extensively studied in both lithium-ion and sodium-ion based electrolyte systems. For practical applications, a cost-effective SMRT reaction-based aqueous system was demonstrated. Along with the above studies, multiple operando or in-situ spectroelectrochemical methods were also developed, which provide insightful information about the mechanism and kinetics. Based on the kinetic studies on different systems, the implications and prospective power capability of SMRT-based RFBs for large-scale energy storage applications were also discussed. | |
dc.language.iso | en | |
dc.subject | energy storage, redox flow battery, redox targeting reaction, operando measurement, electrochemistry, spectroelectrochemical method | |
dc.type | Thesis | |
dc.contributor.department | MATERIALS SCIENCE AND ENGINEERING | |
dc.contributor.supervisor | Qing Wang | |
dc.description.degree | Ph.D | |
dc.description.degreeconferred | DOCTOR OF PHILOSOPHY (FOE) | |
dc.identifier.orcid | 0000-0001-9843-1439 | |
Appears in Collections: | Ph.D Theses (Open) |
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File | Description | Size | Format | Access Settings | Version | |
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Zhou Mingyue_ZhouM.pdf | 8.63 MB | Adobe PDF | OPEN | None | View/Download |
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