Please use this identifier to cite or link to this item:
|Title:||Highly dispersed zinc phosphate microdomains in mesoporous silica||Authors:||Bhaumik, A.
|Issue Date:||Feb-2005||Citation:||Bhaumik, A., Samanta, S., Mal, N.K., Kumar, P., Manna, A. (2005-02). Highly dispersed zinc phosphate microdomains in mesoporous silica. Chemical Engineering Science 60 (3) : 839-843. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ces.2004.09.048||Abstract:||In situ immobilization of crystalline zinc phosphate nuclei in the mesoporous silica material resulted in a highly ordered 2D-hexagonal mesoporous material with evenly dispersed crystalline NaZnPO 4 microdomains in its matrix using the self-assembly of cationic surfactant under hydrothermal synthesis condition. Four samples with different Si:Zn:P:Na mole ratios have been prepared. X-ray diffraction (XRD) patterns of the as-synthesized as well as template-free samples indicated the presence of mesophase in each case. N 2 adsorption data indicated mesoporosity in the samples together with the existence of crystalline NaZnPO 4 phase for the materials synthesized with Si/Zn mole ratio 5-12. 29Si MAS NMR results showed high value of the Q 4/Q 3 ratio in these materials suggesting highly crosslinked structure. © 2004 Elsevier Ltd. All rights reserved.||Source Title:||Chemical Engineering Science||URI:||http://scholarbank.nus.edu.sg/handle/10635/132712||ISSN:||00092509||DOI:||10.1016/j.ces.2004.09.048|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Apr 25, 2019
WEB OF SCIENCETM
checked on Apr 17, 2019
checked on Apr 22, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.