Please use this identifier to cite or link to this item: https://doi.org/10.1002/ejic.200300835
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dc.title3,11,19-Trithia[3.3.3]pyridinophane: Structural diversity in its transition metal complexes
dc.contributor.authorVetrichelvan, M.
dc.contributor.authorLai, Y.-H.
dc.contributor.authorMok, K.F.
dc.date.accessioned2014-12-02T06:52:23Z
dc.date.available2014-12-02T06:52:23Z
dc.date.issued2004-05-17
dc.identifier.citationVetrichelvan, M., Lai, Y.-H., Mok, K.F. (2004-05-17). 3,11,19-Trithia[3.3.3]pyridinophane: Structural diversity in its transition metal complexes. European Journal of Inorganic Chemistry (10) : 2086-2095. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.200300835
dc.identifier.issn14341948
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/114290
dc.description.abstractThe pyridine-containing aza-thia macrocycle 3,11,19-trithia-[3.3.3] pyridinophane (10) and its complexes with NiII, PdII, CuI, AgI and HgII were synthesised and their crystal structures were determined. The NiII and HgII complexes (11, 12) are mononuclear with 10 serving as an unusual quinquedentate ligand. The CuI complex 13 is also mononuclear with 10 being tetra-coordinated to a tetrahedral CuI. Palladium(II) forms a binuclear complex 14 which exists as an inorganic zwitterion and both Pd II metal ions adopt the expected square-planar geometry with facial coordination, Silver(I). forms one-dimensional coordination polymers (15 and 16) with 10 and these exhibit two different coordination modes, namely tetrahedral and trigonal planar. It was found that the macrocycle 10 did not show any selectivity among a series of metal ions. The electronic and redox properties of several complexes were studied. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/ejic.200300835
dc.sourceScopus
dc.subjectCoordination polymers
dc.subjectMacrocycles
dc.subjectStructural diversity
dc.subjectTransition metals
dc.subjectZwitterions
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.contributor.departmentSINGAPORE-MIT ALLIANCE
dc.description.doi10.1002/ejic.200300835
dc.description.sourcetitleEuropean Journal of Inorganic Chemistry
dc.description.issue10
dc.description.page2086-2095
dc.description.codenEJICF
dc.identifier.isiut000221590900016
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