Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/113211

DC Field	Value
dc.title	Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]
dc.contributor.author	Sampanthar, J.T.
dc.contributor.author	Vittal, J.J.
dc.date.accessioned	2014-11-30T06:41:01Z
dc.date.available	2014-11-30T06:41:01Z
dc.date.issued	2001
dc.identifier.citation	Sampanthar, J.T.,Vittal, J.J. (2001). Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]. Main Group Metal Chemistry 24 (2) : 127-128. ScholarBank@NUS Repository.
dc.identifier.issn	07921241
dc.identifier.uri	http://scholarbank.nus.edu.sg/handle/10635/113211
dc.description.abstract	Reaction of CdCl 2 with 1,4-diazabicyclo[2,2,2]octane (dabco) in CH 2Cl 2 solvent gave a neutral binuclear chloride bridged cadmium (II) complex, [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2], 1 which was characterized by 1H and 13C NMR spectroscopy in solution and by X-ray crystallography in the solid state. In 1, the Cd(II) centers are bonded to two terminal and two doubly bridging chloride atoms and a nitrogen atom of the alkylated dabco ligand to have trigonal bipyramidal geometry.
dc.source	Scopus
dc.type	Article
dc.contributor.department	CHEMISTRY
dc.contributor.department	CHEMICAL AND PROCESS ENGINEERING CENTRE
dc.description.sourcetitle	Main Group Metal Chemistry
dc.description.volume	24
dc.description.issue	2
dc.description.page	127-128
dc.description.coden	MGMCE
dc.identifier.isiut	NOT_IN_WOS
Appears in Collections:	Staff Publications

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