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Title: Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]
Authors: Sampanthar, J.T. 
Vittal, J.J. 
Issue Date: 2001
Citation: Sampanthar, J.T.,Vittal, J.J. (2001). Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]. Main Group Metal Chemistry 24 (2) : 127-128. ScholarBank@NUS Repository.
Abstract: Reaction of CdCl 2 with 1,4-diazabicyclo[2,2,2]octane (dabco) in CH 2Cl 2 solvent gave a neutral binuclear chloride bridged cadmium (II) complex, [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2], 1 which was characterized by 1H and 13C NMR spectroscopy in solution and by X-ray crystallography in the solid state. In 1, the Cd(II) centers are bonded to two terminal and two doubly bridging chloride atoms and a nitrogen atom of the alkylated dabco ligand to have trigonal bipyramidal geometry.
Source Title: Main Group Metal Chemistry
ISSN: 07921241
Appears in Collections:Staff Publications

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