Please use this identifier to cite or link to this item: https://doi.org/10.1109/20.951353
Title: Structure and magnetic properties of iron-based cyanide compounds
Authors: Ding, J. 
Ng, C.W.
Shi, Y. 
Keywords: Cyanide compounds
Mössbauer spectroscopy
Molecular magnet
Photo-luminescence
Issue Date: Jul-2001
Citation: Ding, J., Ng, C.W., Shi, Y. (2001-07). Structure and magnetic properties of iron-based cyanide compounds. IEEE Transactions on Magnetics 37 (4 I) : 2938-2940. ScholarBank@NUS Repository. https://doi.org/10.1109/20.951353
Abstract: The M1.5[Fe(CN)6]·zH2O powders with M = Ni, Co, Cu and Zn and z = 4 - 7 were prepared by co-precipitation. A structural change was found after heat treatment at a temperature in the range of 100-200 °C. Mössbauer and magnetic measurements have shown that the FeIII-CN-MII state was the major structure in the co-precipitated form, while the FeII-CN-MIII bond was formed in the annealed samples. The stable FeII-CN-MIII state could convert into a metastable FeIII-CN-MII state accompanied by two peaks in UV-visible spectra. A broad peak was observed in the photo-luminensence spectra, indicating the potential for optical applications.
Source Title: IEEE Transactions on Magnetics
URI: http://scholarbank.nus.edu.sg/handle/10635/107306
ISSN: 00189464
DOI: 10.1109/20.951353
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