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Title: Nanocrystalline W-doped SrBi 2Ta 2O 9 of layered perovskite structure derived from mechanical activation
Authors: Toh, W.S.
Zhou, Z.H. 
Xue, J.M. 
Wang, J. 
Barber, Z.H.
Evetts, J.E.
Keywords: Ceramics
Mechanical Activation
SrBi 2Ta 1.8W 0.2O 9
W-Doped SrBi 2Ta 2O 9
Issue Date: 2005
Citation: Toh, W.S.,Zhou, Z.H.,Xue, J.M.,Wang, J.,Barber, Z.H.,Evetts, J.E. (2005). Nanocrystalline W-doped SrBi 2Ta 2O 9 of layered perovskite structure derived from mechanical activation. Journal of Metastable and Nanocrystalline Materials 23 : 59-62. ScholarBank@NUS Repository.
Abstract: To study the effects of doping the layered perovskite SrBi 2Ta 2O 9 with an appropriate amount of tungsten, both undoped and W-doped SrBi 2Ta 2O 9 (SBT) of nanocrystallinity were synthesized by mechanical activation of constituent oxides of strontium oxide, bismuth oxide, tantalum oxide and tungsten oxide at room temperature. A nanocrystalline single perovskite phase was observed in SrBi 2(Ta 1-xW x) 2O 9 with up to x=0.1. SrBi 2(Ta 0.9W 0.1)O 9 shows a higher Curie temperature than that of undoped SBT, although it exhibits a very similar layered perovskite structure. The ferroelectric and impedance behaviors of SrBi 2(Ta 0.9W 0.1) 2O 9 were studied over a range of test temperatures and frequencies, in order to understand the effects of W-doping in SBT, given that W exhibits a similar ionic size to Ta but with a variable valence.
Source Title: Journal of Metastable and Nanocrystalline Materials
ISSN: 14226375
Appears in Collections:Staff Publications

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