Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/106346
DC FieldValue
dc.titleSmall ligands-induced synthesis of cadmium complexes with N,N-dibenzyl dithiocarbamate and their crystal structures
dc.contributor.authorFan, J.
dc.contributor.authorWei, F.-X.
dc.contributor.authorZhang, W.-G.
dc.contributor.authorYin, X.
dc.contributor.authorLai, C.-S.
dc.contributor.authorTiekink, E.R.T.
dc.date.accessioned2014-10-29T01:58:40Z
dc.date.available2014-10-29T01:58:40Z
dc.date.issued2007-09-28
dc.identifier.citationFan, J.,Wei, F.-X.,Zhang, W.-G.,Yin, X.,Lai, C.-S.,Tiekink, E.R.T. (2007-09-28). Small ligands-induced synthesis of cadmium complexes with N,N-dibenzyl dithiocarbamate and their crystal structures. Acta Chimica Sinica 65 (18) : 2014-2018. ScholarBank@NUS Repository.
dc.identifier.issn05677351
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/106346
dc.description.abstractA Cd(II) adduct [Cd(DBTC)2(4,4'-bipy)] (2) was synthesized by mixing 4,4'-bipyridyl with the precursor [Cd(DBTC)2]2 (1) (DBTC=N,N-dibenzyl dithiocarbamate anion) and characterized by X-ray crystallography structural analysis and IR spectra respectively. The dimer complex [Cd(DBTC)2]2 (1) has been destroyed to produce new adducts after adding new small ligands. The structure of [Cd(DBTC)2py] (3) obtained by adding pyridine into [Cd(DBTC)2]2 (1) was showed as mononuclear complex and it was interesting that [Cd(DBTC)2(4,4'-bipy)] (2) obtained by adding 4,4'-bipy was showed as a 1-D chain coordination polymer, to the best of our knowledge, which has been scarcely reported in dithiocarbamate metal complexes. Spacer-induced self-assembly of Cd(II) complexes has been successfully carried out by adding the suitable small molecule ligands. The effect on the structures of Cd(II) and Zn(II) complexes by adding different spacers such as pyridine and 4,4'-bipy has been also discussed.
dc.sourceScopus
dc.subjectAssembly
dc.subjectCadmium complex
dc.subjectCrystal structure
dc.subjectDithiocarbamate
dc.typeArticle
dc.contributor.departmentPHARMACY
dc.description.sourcetitleActa Chimica Sinica
dc.description.volume65
dc.description.issue18
dc.description.page2014-2018
dc.identifier.isiutNOT_IN_WOS
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.