Selective dissociation of 4-Chloroaniline on the Si(111)-7×7 Surface through N-H bond breakage
Ying, H.C. Yan, X.S. Dong, D. Hai, H.T. Shuai, W. Guo, Q.X.
Ying, H.C.
Yan, X.S.
Dong, D.
Hai, H.T.
Guo, Q.X.
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Abstract
The covalent attachment of 4-chloroaniline on the Si(111)-7×7 surface was investigated by using a combination of X-ray photoelectron spectroscopy (XPS), high-resolution electron energy loss spectroscopy (HREELS), and density functional theory (DFT) calculations. The HREELS spectra suggest that one of the N-H bonds dissociates to form Si-N and Si-H bonds with the phenyl ring and the C-Cl bond unperturbed upon chemisorption. The XPS results confirm that only the NH2 group participates in the surface binding. This binding mode and surface reaction pathway are further supported by the DFT calculation. The resulting chlorobenene-like structure on Si(111)-7×7 can be employed for further photochemical modification and functionalization. © 2009 American Chemical Society.
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Journal of Physical Chemistry C
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Date
2009-03-12
DOI
10.1021/jp8096549
Type
Article