Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene
Tan, Y.L.K. Leong, W.K.
Tan, Y.L.K.
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Abstract
The heteronuclear cluster RuOs3(μ-H)2(CO)13 (1) reacts with indene under thermal activation to afford the novel clusters RuOs3(μ-H)(CO)9(μ-CO)2(η 5-C9H7) (3), RuOs3(μ-H)(CO)9(μ3,η 5:η2:η2-C9H7) (4) and Ru2Os3(μ-H)(CO)11(μ3, η5:η2:η2-C9H 7) (5), the latter two possessing indenyl ligands in the μ3,η5:η2:η2 bonding mode. Cluster 5 exists as a mixture of two isomers. The inter-relationship among the clusters has also been investigated. © 2006 Elsevier B.V. All rights reserved.
Keywords
Heterometallic clusters, Indene, Isomers, Osmium, Ruthenium
Source Title
Journal of Organometallic Chemistry
Publisher
Series/Report No.
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Date
2007-01-15
DOI
10.1016/j.jorganchem.2006.10.010
Type
Article