Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction
Peedikakkal, A.M.P. Peh, C.S.Y. Koh, L.L. Vittal, J.J.
Peedikakkal, A.M.P.
Peh, C.S.Y.
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Abstract
The rctt isomer of tetrapyridylcyclobutane prepared from the solid-state [2 + 2] cycloaddition reaction of [bpeH2]̇2CF3CO 2 [bpe = 1,2-bis(4-pyridyl)ethene] undergoes isomerization reaction to the rtct isomer in 100% yield, and this tetrahedral tetrapyridyl ligand forms two metal-organic frameworks having ptt and pts topology. © 2010 American Chemical Society.
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Inorganic Chemistry
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Date
2010-08-02
DOI
10.1021/ic100853h
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Article