Development of a fluorous, oxime-based palladacycle for microwave-promoted carbon-carbon coupling reactions in aqueous media
Susanto, W. Chu, C.-Y. Ang, W.J. Chou, T.-C. Lo, L.-C. Lam, Y.
Susanto, W.
Chu, C.-Y.
Ang, W.J.
Chou, T.-C.
Lo, L.-C.
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Abstract
A thermally stable, fluorous oxime-based palladacycle has been developed and was shown to efficiently promote various carbon-carbon bond formation reactions (Suzuki-Miyaura, Sonogashira and Stille) in aqueous media under microwave irradiation. The palladacycle gave extremely low levels of Pd leaching and could be reused five times with no significant loss of activity. © 2012 The Royal Society of Chemistry.
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Green Chemistry
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Date
2012-01
DOI
10.1039/c1gc16108c
Type
Article