An unusual approach to the synthesis of enantiomerically cis linear homoallylic alcohols based on the steric interaction mechanism of camphor scaffold
Lee, C.-L.K. Lee, C.-H.A. Tan, K.-T. Loh, T.-P.
Lee, C.-L.K.
Lee, C.-H.A.
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Abstract
Camphor is used as the chiral auxiliary for the enantioselective synthesis of cis linear homoallylic alcohols. A range of catalysts, aldehydes, and solvents were investigated to obtain the optimum yield, enantioselectivity, and cis olefinic geometry.
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Source Title
Organic Letters
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Date
2004-04-15
DOI
10.1021/ol049633z
Type
Article