Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0167-2738(02)00072-3
Title: Spinel phases, LiM1/6Mn11/6O4 (M=Co, CoAl, CoCr, CrAl), as cathodes for lithium-ion batteries
Authors: Shaju, K.M.
Subba Rao, G.V. 
Chowdari, B.V.R. 
Keywords: Cathodes
Lithium-ion batteries
Spinel phases
Issue Date: Jun-2002
Citation: Shaju, K.M., Subba Rao, G.V., Chowdari, B.V.R. (2002-06). Spinel phases, LiM1/6Mn11/6O4 (M=Co, CoAl, CoCr, CrAl), as cathodes for lithium-ion batteries. Solid State Ionics 148 (3-4) : 343-350. ScholarBank@NUS Repository. https://doi.org/10.1016/S0167-2738(02)00072-3
Abstract: Pure and substituted spinels, LiM1/6Mn11/6O4 (M=Co, (Co,Al), (Co,Cr), (Cr,Al)), were prepared, characterised by X-ray diffraction (XRD) and X-ray photoelectron spectra (XPS) and their cathodic performance evaluated. The Mn 2p3/2 XPS analysis shows a decrease in Mn3+ concentration by substitution. The cyclic voltammograms and the charge-discharge profiles of the M-substituted compounds show an indication of structural stabilisation, a decrease in the values of charge and discharge capacities, but a considerable improvement of capacity retention at room temperature as well as at 50°C. © 2002 Elsevier Science B.V. All rights reserved.
Source Title: Solid State Ionics
URI: http://scholarbank.nus.edu.sg/handle/10635/98893
ISSN: 01672738
DOI: 10.1016/S0167-2738(02)00072-3
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