Please use this identifier to cite or link to this item:
|Title:||Synthesis, crystal structure and third-order optical nonlinearity of a 'flywheel'-shaped cluster, [MoS4Cu3(dppm)3][BF4]·2H2O|
Nonlinear optical properties
|Citation:||Tan, W., Zheng, H., Jin, Q., Jin, G., Ji, W., Long, D., Xin, X. (2000-07-01). Synthesis, crystal structure and third-order optical nonlinearity of a 'flywheel'-shaped cluster, [MoS4Cu3(dppm)3][BF4]·2H2O. Polyhedron 19 (13) : 1545-1549. ScholarBank@NUS Repository. https://doi.org/10.1016/S0277-5387(00)00399-5|
|Abstract:||The title compound [MoS4Cu3(dppm)3][BF4]]·2H2O (dppm = Ph2PCH2PPh2) was synthesized for nonlinear optical studies by the reaction of (Et4N)2MoS4 and [Cu2(dppm)2(MeCN)4][BF4]2 in CH3CN solution. Single-crystal X-ray analysis revealed that three copper atoms and the MoS4/2- form a distorted 'flywheel' array with W-Cu separations of 2.7754(14), 2.792(2) and 2.820 (2) Å. The third-order nonlinear optical properties were investigated by a Z-scan technique with 7 ns laser pulses at 532 nm. It was observed that the nonlinear absorption is very small, but it has considerable third-order large nonlinear refractive index. (C) 2000 Elsevier Science Ltd.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Sep 18, 2018
WEB OF SCIENCETM
checked on Sep 3, 2018
checked on Sep 21, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.