Please use this identifier to cite or link to this item:
|Title:||Syntheses, crystal structures and non-linear optical properties of two novel windmill-shaped clusters: [M2Pd4S8(dppm)2]·4DMF (M = W or Mo)|
|Citation:||Zheng, H., Leung, W.-H., Tan, W., Long, D., Ji, W., Chen, J., Xin, F., Xin, X. (2000). Syntheses, crystal structures and non-linear optical properties of two novel windmill-shaped clusters: [M2Pd4S8(dppm)2]·4DMF (M = W or Mo). Journal of the Chemical Society, Dalton Transactions (13) : 2145-2149. ScholarBank@NUS Repository. https://doi.org/10.1039/b000616p|
|Abstract:||Novel cluster compounds [M2Pd4S8(dppm)2]·4DMF (M = W 1 or Mo 2) were synthesized by the reaction of [NEt4]2[MS4] and [Pd(dppm)Cl2] (dppm = Ph2PCH2PPh2) in CH2Cl2 and CH3CN, and their crystal structures have been characterized by X-ray diffraction. Both clusters have novel new skeletal structures with eight atoms in a plane. The non-linear optical properties of 1 were studied with a 7 ns pulsed laser at 532 nm. The effective third-order non-linearities were determined yielding a2 = 1.2 × 10-6 cm W-1 M-1 and n2 = -1.5 × 10-10 cm2 W-1 M-1. Compound 1 exhibits a considerably large self-defocusing property. © The Royal Society of Chemistry 2000.|
|Source Title:||Journal of the Chemical Society, Dalton Transactions|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jul 13, 2018
WEB OF SCIENCETM
checked on Jun 18, 2018
checked on Jun 8, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.