Please use this identifier to cite or link to this item:
|Title:||Size-dependent formation enthalpy of nanocompounds|
|Authors:||Liang, L.H. |
|Citation:||Liang, L.H., Yang, G.W., Li, B. (2005-08-25). Size-dependent formation enthalpy of nanocompounds. Journal of Physical Chemistry B 109 (33) : 16081-16083. ScholarBank@NUS Repository. https://doi.org/10.1021/jp0528461|
|Abstract:||A quantitative thermodynamic model for the size-dependent formation enthalpy of nanocompounds is proposed. The model reveals that the thermal stability of nanocompounds decreases because of the size dependence of formation enthalpy when the size of these nanostructures decreases. This stability loss is related to some general phenomena such as interface alloying of immiscible systems and phase segregation of miscible systems with reducing system sizes. The predictions from the model are in agreement with the results from density function theory calculation for MgH2, the experimental measurement of SnTe nanoparticles, and quantum chemistry consideration. © 2005 American Chemical Society.|
|Source Title:||Journal of Physical Chemistry B|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Mar 20, 2019
WEB OF SCIENCETM
checked on Mar 5, 2019
checked on Mar 8, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.