Please use this identifier to cite or link to this item:
|Title:||Resonant processes and Coulomb interactions in (C59 N)2|
|Citation:||Schulte, K., Wang, L., Moriarty, P.J., Prassides, K., Tagmatarchis, N. (2007). Resonant processes and Coulomb interactions in (C59 N)2. Journal of Chemical Physics 126 (18) : -. ScholarBank@NUS Repository. https://doi.org/10.1063/1.2730787|
|Abstract:||We have determined the on-site molecular Coulomb interaction energy U of a (C59 N)2 bulk film and find values ranging from 1.10±0.10 eV for the highest occupied molecular orbital to 1.35±0.10 eV for the deeper lying orbitals, comparable to values found in C60. The on-site Coulomb interaction between a carbon core hole and valence electrons, Uc, is, however, substantially lower than in C60 at 1.35±0.07 eV. Resonant photoemission (RESPES) results show a weakened participator decay channel, especially around the N 1s threshold, where resonance of the highest occupied molecular orbital shoulder is absent. Near-edge x-ray absorption fine structure and constant initial state measurements, taken in parallel with the RESPES data, indicate, however, that matrix element effects cannot be ruled out. © 2007 American Institute of Physics.|
|Source Title:||Journal of Chemical Physics|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Dec 11, 2018
WEB OF SCIENCETM
checked on Nov 26, 2018
checked on Dec 7, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.