Please use this identifier to cite or link to this item: https://doi.org/10.1039/b211563h
Title: Investigations into the interaction between hydrogen and calcium nitride
Authors: Xiong, Z. 
Chen, P. 
Wu, G. 
Lin, J. 
Tan, K.L. 
Issue Date: 1-Jul-2003
Citation: Xiong, Z., Chen, P., Wu, G., Lin, J., Tan, K.L. (2003-07-01). Investigations into the interaction between hydrogen and calcium nitride. Journal of Materials Chemistry 13 (7) : 1676-1680. ScholarBank@NUS Repository. https://doi.org/10.1039/b211563h
Abstract: The interaction between hydrogen and α-Ca3N2 has been investigated by temperature programmed adsorption-desorption and pressure-composition (P-C) isotherms and also by X-ray powder diffraction. We find that hydrogen adsorption by Ca3N2 begins at temperatures around 300 °C. Approximately 3.5 H atoms can be adsorbed by one Ca3N2 molecule. Only half of the adsorbed hydrogen can be desorbed at temperatures above 350 °C, Addition of CaH2 enhances the reversibility of H-adsorption in the Ca3N2 sample. As demonstrated in the present work, almost all of the hydrogen adsorbed by the Ca3N2-CaH2 sample (molar ratio 1:1) can be released with Ca2NH as the final product.
Source Title: Journal of Materials Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/96989
ISSN: 09599428
DOI: 10.1039/b211563h
Appears in Collections:Staff Publications

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