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https://doi.org/10.1016/j.jpowsour.2006.04.004
Title: | Investigation on chemical reaction between LiAlH4 and LiNH2 | Authors: | Xiong, Z. Wu, G. Hu, J. Chen, P. |
Keywords: | Hydrogen desorption LiAlH4 LiNH2 |
Issue Date: | 13-Sep-2006 | Citation: | Xiong, Z., Wu, G., Hu, J., Chen, P. (2006-09-13). Investigation on chemical reaction between LiAlH4 and LiNH2. Journal of Power Sources 159 (1 SPEC. ISS.) : 167-170. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jpowsour.2006.04.004 | Abstract: | Although the transformation of the tetrahedral [AlH4]- to the octahedral [AlH6]3- occurs at high temperature, it was realized by ball milling (BM) of LiAlH4 at ambient temperature in the presence of LiNH2. Instead of a catalytical role, we found that LiNH2 may react with LiAlH4 to form an intermediate with a 1:1 stoichiometry. Our results show that a total amount of about 8 wt% H2 can be detached from the mixture of LiAlH4-LiNH2 which is potential for an effective hydrogen storage system. Calculations combined with DSC measurements result in a very low enthalpy effect of the H2 release reaction, further implying a possible reversibility in hydrogen storage. © 2006 Elsevier B.V. All rights reserved. | Source Title: | Journal of Power Sources | URI: | http://scholarbank.nus.edu.sg/handle/10635/96987 | ISSN: | 03787753 | DOI: | 10.1016/j.jpowsour.2006.04.004 |
Appears in Collections: | Staff Publications |
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