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|Title:||Investigation on chemical reaction between LiAlH4 and LiNH2|
|Authors:||Xiong, Z. |
|Citation:||Xiong, Z., Wu, G., Hu, J., Chen, P. (2006-09-13). Investigation on chemical reaction between LiAlH4 and LiNH2. Journal of Power Sources 159 (1 SPEC. ISS.) : 167-170. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jpowsour.2006.04.004|
|Abstract:||Although the transformation of the tetrahedral [AlH4]- to the octahedral [AlH6]3- occurs at high temperature, it was realized by ball milling (BM) of LiAlH4 at ambient temperature in the presence of LiNH2. Instead of a catalytical role, we found that LiNH2 may react with LiAlH4 to form an intermediate with a 1:1 stoichiometry. Our results show that a total amount of about 8 wt% H2 can be detached from the mixture of LiAlH4-LiNH2 which is potential for an effective hydrogen storage system. Calculations combined with DSC measurements result in a very low enthalpy effect of the H2 release reaction, further implying a possible reversibility in hydrogen storage. © 2006 Elsevier B.V. All rights reserved.|
|Source Title:||Journal of Power Sources|
|Appears in Collections:||Staff Publications|
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