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|Title:||Analysis of High-Resolution FTIR Spectrum of the ν6Band of H13COOH|
|Authors:||Ong, P.P. |
|Citation:||Ong, P.P., Goh, K.L., Teo, H.H. (1999-04). Analysis of High-Resolution FTIR Spectrum of the ν6Band of H13COOH. Journal of Molecular Spectroscopy 194 (2) : 203-205. ScholarBank@NUS Repository. https://doi.org/10.1006/jmsp.1998.7776|
|Abstract:||The FTIR spectrum of the ν6band of H13COOH has been collected at a resolution of 0.004 cm-1in the frequency range of 1030-1160 cm-1. The ν6band was analyzed to be anA-Bhybrid band and perturbed by the nearby ν8band througha-, andb-Coriolis coupling terms. Using a Watson'sA-reduced Hamiltonian in theIrrepresentation, with the inclusion ofa- andb-Coriolis resonances, a total of 3004 IR transitions of ν6have been analyzed to provide rovibrational constants for thev6= 1 state with a standard deviation of 0.00047 cm-1. The ν6band was found to be centered at 1095.40365 ± 0.00003 cm-1. © 1999 Academic Press.|
|Source Title:||Journal of Molecular Spectroscopy|
|Appears in Collections:||Staff Publications|
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