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|Title:||Supramolecular association in organomercury(II) 1,1-dithiolates. Complementarity between Hg⋯S and hydrogen bonding interactions in organomercury(II) 2-amino-cyclopent-1-ene-1-carbodithioates|
|Authors:||Lai, C.S. |
|Citation:||Lai, C.S., Tiekink, E.R.T. (2003-06-24). Supramolecular association in organomercury(II) 1,1-dithiolates. Complementarity between Hg⋯S and hydrogen bonding interactions in organomercury(II) 2-amino-cyclopent-1-ene-1-carbodithioates. CrystEngComm 5 : 253-261. ScholarBank@NUS Repository. https://doi.org/10.1039/b305363f|
|Abstract:||A survey of the supramolecular associations operating in the crystal structures of organomercury 1,1-dithiolates shows that owing to the presence of Hg⋯S interactions, dimeric, 1-, 2- and 3-dimensional architectures are generated. Introducing hydrogen-bonding functionality into the 1,1-dithiolate ligand allows for the formation of both intra- and intermolecular hydrogen bonds as well as Hg⋯S interactions, so that 2- and 3-dimensional architectures are formed that are distinct for each of the two polymorphic forms of MeHg(S2CC5H6NH2-2) and for PhHg(S2CC5H6NH2-2). © The Royal Society of Chemistry 2003.|
|Appears in Collections:||Staff Publications|
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