Please use this identifier to cite or link to this item: https://doi.org/10.1039/b305363f
Title: Supramolecular association in organomercury(II) 1,1-dithiolates. Complementarity between Hg⋯S and hydrogen bonding interactions in organomercury(II) 2-amino-cyclopent-1-ene-1-carbodithioates
Authors: Lai, C.S. 
Tiekink, E.R.T. 
Issue Date: 24-Jun-2003
Citation: Lai, C.S., Tiekink, E.R.T. (2003-06-24). Supramolecular association in organomercury(II) 1,1-dithiolates. Complementarity between Hg⋯S and hydrogen bonding interactions in organomercury(II) 2-amino-cyclopent-1-ene-1-carbodithioates. CrystEngComm 5 : 253-261. ScholarBank@NUS Repository. https://doi.org/10.1039/b305363f
Abstract: A survey of the supramolecular associations operating in the crystal structures of organomercury 1,1-dithiolates shows that owing to the presence of Hg⋯S interactions, dimeric, 1-, 2- and 3-dimensional architectures are generated. Introducing hydrogen-bonding functionality into the 1,1-dithiolate ligand allows for the formation of both intra- and intermolecular hydrogen bonds as well as Hg⋯S interactions, so that 2- and 3-dimensional architectures are formed that are distinct for each of the two polymorphic forms of MeHg(S2CC5H6NH2-2) and for PhHg(S2CC5H6NH2-2). © The Royal Society of Chemistry 2003.
Source Title: CrystEngComm
URI: http://scholarbank.nus.edu.sg/handle/10635/95581
ISSN: 14668033
DOI: 10.1039/b305363f
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