Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0022-328X(02)01977-0
Title: Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)
Authors: Goh, L.Y. 
Teo, M.E.
Khoo, S.B. 
Leong, W.K. 
Vittal, J.J. 
Issue Date: 16-Dec-2002
Citation: Goh, L.Y., Teo, M.E., Khoo, S.B., Leong, W.K., Vittal, J.J. (2002-12-16). Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III). Journal of Organometallic Chemistry 664 (1-2) : 161-169. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(02)01977-0
Abstract: The reaction of [Cp*RuCl2]2 (7) (Cp* = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95556
ISSN: 0022328X
DOI: 10.1016/S0022-328X(02)01977-0
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