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|Title:||Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)|
|Authors:||Goh, L.Y. |
|Source:||Goh, L.Y., Teo, M.E., Khoo, S.B., Leong, W.K., Vittal, J.J. (2002-12-16). Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III). Journal of Organometallic Chemistry 664 (1-2) : 161-169. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(02)01977-0|
|Abstract:||The reaction of [Cp*RuCl2]2 (7) (Cp* = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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