Please use this identifier to cite or link to this item:
|Title:||α,ω-bis(trichlorostannyl)alkanes as bis(monodentate) Lewis acids toward halide ions|
|Citation:||Zobel, B., Duthie, A., Dakternieks, D., Tiekink, E.R.T. (2001-07-23). α,ω-bis(trichlorostannyl)alkanes as bis(monodentate) Lewis acids toward halide ions. Organometallics 20 (15) : 3347-3350. ScholarBank@NUS Repository. https://doi.org/10.1021/om010246s|
|Abstract:||The reactions between X3Sn(CH2)nSnX3 (X = Cl, Br; n = 1, 3, 4, 8) and halide in solution are described. 119Sn NMR spectroscopy (CD2Cl2) indicates formation of five-coordinate dinuclear 1:2 adducts, [X4Sn(CH2)nSnX4]2-, with chloride and bromide. A trigonal-bipyramidal geometry has been confirmed in the solid state for the compound having X = Cl and n = 4. In contrast, fluoride reacts with X3Sn(CH2)nSnX3 to give six-coordinate tin species, [F5Sn(CH2)nSnF5].4- There was no evidence indicating that the tin atoms could act as a bidentate acid.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 16, 2019
WEB OF SCIENCETM
checked on Jan 9, 2019
checked on Dec 28, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.