Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/95388
Title: UPS study of spirosilane
Authors: Novak, I. 
Kovaĉa, B.
Keywords: Photoelectron Spectroscopy
Spiroconjugation
Issue Date: Apr-2003
Citation: Novak, I.,Kovaĉa, B. (2003-04). UPS study of spirosilane. Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences 58 (4) : 217-219. ScholarBank@NUS Repository.
Abstract: The electronic structure of 2,7-dimethyl-5-silaspiro[4,4]nona-2,7-diene has been investigated by UV photoelectron spectroscopy (UPS). The analysis of the spectra has been performed by DFT and ROVGF calculations and comparison with the UPS spectra of related compounds. An unusual π-orbital degeneracy in this molecule of C2-symmetry was observed. The spiroconjugation is quenched, and the reasons are discussed.
Source Title: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
URI: http://scholarbank.nus.edu.sg/handle/10635/95388
ISSN: 09320784
Appears in Collections:Staff Publications

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