The reaction of pentafluoronitrosobenzene with Os3(CO)12: synthesis and X-ray crystal structure of [Os3(CO)9(μ3-NC6F 5)2]
Ang, H.G. Kwik, W.L. Ong, K.K.
Ong, K.K.
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Abstract
The reaction of pentafluoronitrosobenzene with Os3(CO)12 at 125 °C in octane leads to the formation of a new bis(pentafluorophenylimido)triosmium cluster, [Os3(CO)9(μ3- NC6F5)2] (I). Cluster I has been shown by X-ray crystallographic studies to consist of an open triosmium framework capped by triply bridging pentafluorophenylimido ligands. © 1992.
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Journal of Fluorine Chemistry
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1992-01
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