Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/95258
Title: The reaction of pentafluoronitrosobenzene with Os3(CO)12: synthesis and X-ray crystal structure of [Os3(CO)9(μ3-NC6F 5)2]
Authors: Ang, H.G. 
Kwik, W.L. 
Ong, K.K.
Issue Date: Jan-1992
Citation: Ang, H.G.,Kwik, W.L.,Ong, K.K. (1992-01). The reaction of pentafluoronitrosobenzene with Os3(CO)12: synthesis and X-ray crystal structure of [Os3(CO)9(μ3-NC6F 5)2]. Journal of Fluorine Chemistry 56 (1) : 45-49. ScholarBank@NUS Repository.
Abstract: The reaction of pentafluoronitrosobenzene with Os3(CO)12 at 125 °C in octane leads to the formation of a new bis(pentafluorophenylimido)triosmium cluster, [Os3(CO)9(μ3- NC6F5)2] (I). Cluster I has been shown by X-ray crystallographic studies to consist of an open triosmium framework capped by triply bridging pentafluorophenylimido ligands. © 1992.
Source Title: Journal of Fluorine Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95258
ISSN: 00221139
Appears in Collections:Staff Publications

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