Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2013.04.037
Title: The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex
Authors: Mak, K.H.G.
Fan, W.Y. 
Sridevi, V.S.
Leong, W.K.
Keywords: C-C coupling
Conjugated enyne
Iridium h3-tetraenyl
Issue Date: 1-Sep-2013
Citation: Mak, K.H.G., Fan, W.Y., Sridevi, V.S., Leong, W.K. (2013-09-01). The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex. Journal of Organometallic Chemistry 739 : 52-56. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2013.04.037
Abstract: Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C-C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally. © 2013 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95255
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2013.04.037
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