Please use this identifier to cite or link to this item: https://doi.org/10.1021/om401013a
Title: The dithiolate-bridged diiron hexacarbonyl complex Na2[(μ- SCH2CH2COO)Fe(CO)3]2 as a water-soluble photoCORM
Authors: Poh, H.T.
Sim, B.T.
Chwee, T.S.
Leong, W.K.
Fan, W.Y. 
Issue Date: 24-Feb-2014
Citation: Poh, H.T., Sim, B.T., Chwee, T.S., Leong, W.K., Fan, W.Y. (2014-02-24). The dithiolate-bridged diiron hexacarbonyl complex Na2[(μ- SCH2CH2COO)Fe(CO)3]2 as a water-soluble photoCORM. Organometallics 33 (4) : 959-963. ScholarBank@NUS Repository. https://doi.org/10.1021/om401013a
Abstract: The water-soluble dimercaptopropanoate-bridged diiron hexacarbonyl complex Na2[(μ-SCH2CH2COO)Fe(CO)3] 2 has been prepared, and the X-ray crystal structure and infrared, UV-visible, and ESI spectra of the complex have been obtained. The complex is shown to behave as a photoCORM, whereby all six CO ligands are released within 30 min of visible-light irradiation. Gas-phase FTIR spectroscopy has been used to quantify the release of CO into the headspace above the aqueous solution. The resulting product, tentatively assigned to an iron thiolate salt, is also water-soluble. Cell viability studies show that Na2[(μ-SCH 2CH2COO)Fe(CO)3]2 is not cytotoxic toward normal epithelial cells. © 2014 American Chemical Society.
Source Title: Organometallics
URI: http://scholarbank.nus.edu.sg/handle/10635/95223
ISSN: 02767333
DOI: 10.1021/om401013a
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