Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jcis.2008.08.059
Title: The deposition of osmium carbonyl clusters onto inorganic oxide surfaces: A ToF-SIMS and IR spectroscopic study of the surface species
Authors: Li, C.
Leong, W.K. 
Keywords: Bifunctional ligand
Cluster
Inorganic oxide
Osmium
ToF-SIMS
Issue Date: 1-Dec-2008
Citation: Li, C., Leong, W.K. (2008-12-01). The deposition of osmium carbonyl clusters onto inorganic oxide surfaces: A ToF-SIMS and IR spectroscopic study of the surface species. Journal of Colloid and Interface Science 328 (1) : 29-33. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jcis.2008.08.059
Abstract: The interaction between the osmium clusters [Os3(CO)12], [Os3(CO)10(μ-H)2], [Os3(CO)10(μ-H)(μ-OH)], and a series containing a free functional group, viz., [Os3(CO)10(μ-H)(μ-S∧ EH)] (where ∧= alkyl chain or an aromatic ring, E = COO, S or O), with SiO2, ZnO and In2O3, was examined by ToF-SIMS and IR spectroscopy. While the interaction with the silica surface is mostly via an O atom or the functional group, the interaction with the ZnO and In2O3 surfaces is more complex. © 2008 Elsevier Inc. All rights reserved.
Source Title: Journal of Colloid and Interface Science
URI: http://scholarbank.nus.edu.sg/handle/10635/95218
ISSN: 00219797
DOI: 10.1016/j.jcis.2008.08.059
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