Please use this identifier to cite or link to this item: https://doi.org/10.1002/ejic.200700072
Title: The aromatization of C5 rings on a heteronuclear cluster
Authors: Tan, Y.L.K.
Weng, K.L. 
Keywords: Carbocyclic rings
Cyclopentadienyl ligands
Heterometallic complexes
Osmium
Ruthenium
Issue Date: 2007
Citation: Tan, Y.L.K., Weng, K.L. (2007). The aromatization of C5 rings on a heteronuclear cluster. European Journal of Inorganic Chemistry (15) : 2151-2160. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.200700072
Abstract: The reaction of the heteronuclear cluster RuOs3(u-H) 2(CO)13 with saturated and unsaturated C5 rings led to the aromatization of the rings to afford the clusters RuOs 3(u-H)(CO)9(μ-CO)2(η5-C 5R4R′). However, the reaction with cyclopentene gave the cluster RuOs3(μ-H)3(CO)11(μ, η1:η2-C5H7) via C-H activation of an sp2 carbon instead. Thermolysis of two of the products, RuOs3(μ-H)(CO)9(μ-CO)2(η 5-Cp′) and RuOs3(μ-H)(CO)9(μ-CO) 2(η5-C5H4SiMe3), led to their isomerization to butterfly clusters. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Source Title: European Journal of Inorganic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95213
ISSN: 14341948
DOI: 10.1002/ejic.200700072
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