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|Title:||The adsorption of N2O on clean and chemically modified Ru(001) surfaces|
|Authors:||Huang, H.H. |
Low index single crystal surfaces
Thermal desorption spectroscopy
|Citation:||Huang, H.H.,Seet, C.S.,Zou, Z.,Xu, G.Q. (1996-06-10). The adsorption of N2O on clean and chemically modified Ru(001) surfaces. Surface Science 356 (1-3) : 181-188. ScholarBank@NUS Repository.|
|Abstract:||The adsorption of N2O on clean, oxygen, deuterium and carbon monoxide modified Ru(001) surfaces was investigated. On the clean surface, three adsorption states have been observed, desorbing at 160-165, 145 and 116-123 K, respectively. On the oxygen modified surface, the presence of oxygen shifts the N2O desorption temperature from 129 K (on a clean surface) to a higher temperature of 173 K (θo = 0.12). The enhanced adsorption of N2O on partially O-covered Ru(004) was also observed. However, on D- and CO-precovered surfaces, the N2O adsorption is destabilized. These results can be accounted for by considering the "through-metal" and the lateral interactions between coadsorbates.|
|Source Title:||Surface Science|
|Appears in Collections:||Staff Publications|
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