Please use this identifier to cite or link to this item:
https://doi.org/10.1016/S0020-1693(03)00146-4
| DC Field | Value | |
|---|---|---|
| dc.title | The 3-thiapentane-1,5-dithiolato-hexamethylbenzene ruthenium(II) complex as a metalloligand to Group 14 elements | |
| dc.contributor.author | Shin, R.Y.C. | |
| dc.contributor.author | Vittal, J.J. | |
| dc.contributor.author | Zhou, Z.-Y. | |
| dc.contributor.author | Koh, L.L. | |
| dc.contributor.author | Goh, L.Y. | |
| dc.date.accessioned | 2014-10-16T08:45:08Z | |
| dc.date.available | 2014-10-16T08:45:08Z | |
| dc.date.issued | 2003-08-06 | |
| dc.identifier.citation | Shin, R.Y.C., Vittal, J.J., Zhou, Z.-Y., Koh, L.L., Goh, L.Y. (2003-08-06). The 3-thiapentane-1,5-dithiolato-hexamethylbenzene ruthenium(II) complex as a metalloligand to Group 14 elements. Inorganica Chimica Acta 352 : 220-228. ScholarBank@NUS Repository. https://doi.org/10.1016/S0020-1693(03)00146-4 | |
| dc.identifier.issn | 00201693 | |
| dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/95211 | |
| dc.description.abstract | The coordination chemistry of [(C6Me6)Ru(tpdt)] (1) (tpdt=3-thiapentane-1,5-dithiolate) towards Group 14 moieties has been studied. The reactions with Ph2MCl2 (M=Ge or Sn) and Ph3MCl (M=Sn or Pb) led to the isolation of [{(η6-C6Me6)Ru}(μ2-η 2:η3-C4H8S3){MCl (η1-C6H5)2}](PF6), [M=Ge (5)(PF6), Sn (6)(PF6)] and [{(η6-C6Me6)Ru}(μ2-η 1:η3-C4H8S3){M (η1-C6H5)3}](PF6) [M=Sn (7)(PF6), Pb (8)(PF6)], respectively. The reaction with Ph2SiCl2 in the presence of NH4PF6 gave a quantitative yield of [(η6-C6Me6)Ru(η3-C 4H9S3)](PF6), (4)(PF6) which converts to [{(η6-C6Me6)Ru}2(MeCN)(μ 2-η2:η3-C4H8S 3)](PF6)2, (3)(PF6)2. The X-ray structures show that 1 can either act as a monodentate metalloligand as in 7 and 8 or a bidentate ligand as in 5 and 6. © 2003 Elsevier Science B.V. All rights reserved. | |
| dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S0020-1693(03)00146-4 | |
| dc.source | Scopus | |
| dc.subject | Arene complexes | |
| dc.subject | Crystal structures | |
| dc.subject | Ruthenium complexes | |
| dc.subject | S-ligand complexes | |
| dc.type | Article | |
| dc.contributor.department | CHEMISTRY | |
| dc.description.doi | 10.1016/S0020-1693(03)00146-4 | |
| dc.description.sourcetitle | Inorganica Chimica Acta | |
| dc.description.volume | 352 | |
| dc.description.page | 220-228 | |
| dc.description.coden | ICHAA | |
| dc.identifier.isiut | 000184727900027 | |
| Appears in Collections: | Staff Publications | |
Show simple item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.