Please use this identifier to cite or link to this item:
https://doi.org/10.1021/ic011181o
| DC Field | Value | |
|---|---|---|
| dc.title | Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au) | |
| dc.contributor.author | Xu, X. | |
| dc.contributor.author | Audi Fong, S.-W. | |
| dc.contributor.author | Li, Z. | |
| dc.contributor.author | Loh, Z.-H. | |
| dc.contributor.author | Zhao, F. | |
| dc.contributor.author | Vittal, J.J. | |
| dc.contributor.author | Henderson, W. | |
| dc.contributor.author | Khoo, S.-B. | |
| dc.contributor.author | Hor, T.S.A. | |
| dc.date.accessioned | 2014-10-16T08:44:52Z | |
| dc.date.available | 2014-10-16T08:44:52Z | |
| dc.date.issued | 2002-12-16 | |
| dc.identifier.citation | Xu, X., Audi Fong, S.-W., Li, Z., Loh, Z.-H., Zhao, F., Vittal, J.J., Henderson, W., Khoo, S.-B., Hor, T.S.A. (2002-12-16). Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au). Inorganic Chemistry 41 (25) : 6838-6845. ScholarBank@NUS Repository. https://doi.org/10.1021/ic011181o | |
| dc.identifier.issn | 00201669 | |
| dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/95188 | |
| dc.description.abstract | Novel electroactive multimetallic compounds based on the {Pt2(μ2-S)2M} core, viz. [Pt2(PPh3)4 (μ3-S)2HgFc]PF6 (1) [Fc = (η5-C5H4)Fe(η5- C5H5)] and [Pt2(PPh3)4 (μ3-S)2Hg2Fc′] (PF6)2 (2) [Fc′ = Fe(η5-C5H4)2], have been synthesized under the guide of electrospray mass spectrometry. The electrochemistry of these ferrocene funtionalized compounds together with the reported [Pt2(PPh3)4 (μ3-S)2HgPPh3] (PF6)2 (3), [Pt2(PPh3)4(μ2-S) (μ3-S)HgPh]PF6 (4), and [Pt2(PPh3)4-(μ2-S) (μ3-S)AuPPh3]PF6 (5) have been investigated using cyclic voltammetry and DFT calculations. These results point to a prominent ligand-based oxidation. | |
| dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/ic011181o | |
| dc.source | Scopus | |
| dc.type | Article | |
| dc.contributor.department | CHEMISTRY | |
| dc.description.doi | 10.1021/ic011181o | |
| dc.description.sourcetitle | Inorganic Chemistry | |
| dc.description.volume | 41 | |
| dc.description.issue | 25 | |
| dc.description.page | 6838-6845 | |
| dc.description.coden | INOCA | |
| dc.identifier.isiut | 000179797700038 | |
| Appears in Collections: | Staff Publications | |
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