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|Title:||Synthesis, characterization and biological activity of dioxouranium(VI) complexes of acyldipyridoxal hydrazones|
|Authors:||Yang, C.-T. |
Solid state structure
|Citation:||Yang, C.-T., Ranford, J.D., Vittal, J.J. (2005). Synthesis, characterization and biological activity of dioxouranium(VI) complexes of acyldipyridoxal hydrazones. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry 35 (1) : 71-82. ScholarBank@NUS Repository. https://doi.org/10.1081/SIM-200047551|
|Abstract:||Four acyl dipyridoxal hydrozones ligands, H4PLn, have been prepared by condensing the ester of the diacids, hydrazine hydrate and pyridoxal hydrochloride in 1:2:2 molar ratio. The UO2 VI complexes of these ligands have been synthesized and characterized by various analytical and spectroscopic methods including X-ray crystallography. The ligands and UO2 VI complexes have been tested for cytotoxicity. The solid-state structure of [(UO2)4(PL 1)2(H2O)4]· 12H2O has been found to be a cyclic tetramer and this may or may not represent the structure of the bulk sample. The structures of bulk 1-4 have been proposed to be polymeric. Copyright © 2005 Taylor & Francis, Inc.|
|Source Title:||Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry|
|Appears in Collections:||Staff Publications|
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