Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2006.03.027
Title: Synthesis and X-ray structures of rhenium(I) carbonyl aminoalkoxide and aminocarboxylate complexes
Authors: Wang, W.
Andy Hor, T.S. 
Yan, Y.K.
Keywords: Amine-oxide
Aminoalkoxide
Aminocarboxylate
Carbonyl
Oxidative alkoxylation
Rhenium
Issue Date: 1-Aug-2006
Citation: Wang, W., Andy Hor, T.S., Yan, Y.K. (2006-08-01). Synthesis and X-ray structures of rhenium(I) carbonyl aminoalkoxide and aminocarboxylate complexes. Inorganica Chimica Acta 359 (11) : 3754-3762. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2006.03.027
Abstract: The complexes [Re{MeN(CH2CH2O)(CH2CH2OH)-κ3N,O,O}(CO)3] (1), [Re{N(CH2CH2O)(CH2CH2OH)2-κ3N,O,O}(CO)3] (2), [Me3NH]2[(OC)3Re{N(CH2CO2)2-κ3N,O,O}CH2CH2{N(CH2CO2)2-κ3N,O,O}Re(CO)3] (3), [Me3NH]2[Re2{μ2-2,6-(O2C)2(C5H3N)-κ3N,O,O}2(CO)6] (4) and [Re2{μ2-2,6-(OCH2)(C5H3N)(CH2OH)-κ2N,O}2(CO)6] (5) were synthesized in high yields via the reactions of [Re2(CO)10] and Me3NO with MeN(CH2CH2OH)2, N(CH2CH2OH)3, EDTA, pyridine-2,6-dicarboxylic acid and pyridine-2,6-dimethanol, respectively. Complexes 1-5 were characterized by IR and 1H NMR spectroscopy, elemental analysis and X-ray crystallography. © 2006 Elsevier B.V. All rights reserved.
Source Title: Inorganica Chimica Acta
URI: http://scholarbank.nus.edu.sg/handle/10635/95111
ISSN: 00201693
DOI: 10.1016/j.ica.2006.03.027
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