Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2005.11.061
Title: Synthesis and structure of some ruthenium-rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene
Authors: Ye, S.
Leong, W.K. 
Keywords: Addition of carboxylic acid
Alkyne
Anti-Markovnikov addition
Catalysis
Heterodinuclear
Rhenium
Ruthenium
Issue Date: 1-Mar-2006
Source: Ye, S., Leong, W.K. (2006-03-01). Synthesis and structure of some ruthenium-rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene. Journal of Organometallic Chemistry 691 (6) : 1216-1222. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.11.061
Abstract: The salt elimination reaction of Na[Re(CO)5] with Cp*Ru(dppm)Cl, CpRu(dppm)Cl or CpRu(CO)2Cl afforded the heterodinuclear species Cp*Ru(μ-CO)2(μ-dppm)Re(CO) 3, Cp(CO)Ru(μ-dppm)Re(CO)4, or Cp(CO) 2RuRe(CO)5, respectively, in moderate yields. An orthometallated species, Cp*(CO)Ru(μ-H)[μ-PhP(C6H 4)CH2PPh2]Re(CO)3, was also obtained from the first reaction. All these heterodinuclear products have been characterised crystallographically. They also showed good catalytic activity for the addition of carboxylic acids to phenylacetylene to afford the anti-Markovnikov products selectively. © 2005 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95101
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2005.11.061
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