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|Title:||Synthesis and structure of some ruthenium-rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene|
|Keywords:||Addition of carboxylic acid|
|Citation:||Ye, S., Leong, W.K. (2006-03-01). Synthesis and structure of some ruthenium-rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene. Journal of Organometallic Chemistry 691 (6) : 1216-1222. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.11.061|
|Abstract:||The salt elimination reaction of Na[Re(CO)5] with Cp*Ru(dppm)Cl, CpRu(dppm)Cl or CpRu(CO)2Cl afforded the heterodinuclear species Cp*Ru(μ-CO)2(μ-dppm)Re(CO) 3, Cp(CO)Ru(μ-dppm)Re(CO)4, or Cp(CO) 2RuRe(CO)5, respectively, in moderate yields. An orthometallated species, Cp*(CO)Ru(μ-H)[μ-PhP(C6H 4)CH2PPh2]Re(CO)3, was also obtained from the first reaction. All these heterodinuclear products have been characterised crystallographically. They also showed good catalytic activity for the addition of carboxylic acids to phenylacetylene to afford the anti-Markovnikov products selectively. © 2005 Elsevier B.V. All rights reserved.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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