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|Title:||Synthesis and properties of polyfluoroalkoxygermanes|
|Authors:||Ang, H.G. |
|Source:||Ang, H.G.,Koh, C.H. (1990). Synthesis and properties of polyfluoroalkoxygermanes. Polyhedron 9 (17) : 2189-2190. ScholarBank@NUS Repository.|
|Abstract:||Two new polyfluoroalkoxygermanes, (CF3)2C(H)OGeH3 (A) and [(CF3)2C(H)O]2GeH2 (B), were synthesized from the reactions of (CF3)2CO and GeH4. The GeO bond in A was cleaved by HCl to give (CF3)2C(H)OH and GeH3Cl. Pyrolysis of both the alkoxygermanes also resulted in the formation of the alcohol, with concomitant deposition of germanium metal. © 1990.|
|Appears in Collections:||Staff Publications|
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