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Title: | Synthesis and properties of polyfluoroalkoxygermanes | Authors: | Ang, H.G. Koh, C.H. |
Issue Date: | 1990 | Citation: | Ang, H.G.,Koh, C.H. (1990). Synthesis and properties of polyfluoroalkoxygermanes. Polyhedron 9 (17) : 2189-2190. ScholarBank@NUS Repository. | Abstract: | Two new polyfluoroalkoxygermanes, (CF3)2C(H)OGeH3 (A) and [(CF3)2C(H)O]2GeH2 (B), were synthesized from the reactions of (CF3)2CO and GeH4. The GeO bond in A was cleaved by HCl to give (CF3)2C(H)OH and GeH3Cl. Pyrolysis of both the alkoxygermanes also resulted in the formation of the alcohol, with concomitant deposition of germanium metal. © 1990. | Source Title: | Polyhedron | URI: | http://scholarbank.nus.edu.sg/handle/10635/95081 | ISSN: | 02775387 |
Appears in Collections: | Staff Publications |
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