Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/95033
DC FieldValue
dc.titleSynthesis and characterization of conducting poly(o-aminobenzyl alcohol) and its copolymers with aniline
dc.contributor.authorChan, H.S.O.
dc.contributor.authorNg, S.C.
dc.contributor.authorSim, W.S.
dc.contributor.authorSeow, S.H.
dc.contributor.authorTan, K.L.
dc.contributor.authorTan, B.T.G.
dc.date.accessioned2014-10-16T08:43:02Z
dc.date.available2014-10-16T08:43:02Z
dc.date.issued1993-01-04
dc.identifier.citationChan, H.S.O.,Ng, S.C.,Sim, W.S.,Seow, S.H.,Tan, K.L.,Tan, B.T.G. (1993-01-04). Synthesis and characterization of conducting poly(o-aminobenzyl alcohol) and its copolymers with aniline. Macromolecules 26 (1) : 144-150. ScholarBank@NUS Repository.
dc.identifier.issn00249297
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95033
dc.description.abstractPolyaniline, poly(aniline-co-o-aminobenzyl alcohol), and poly(o-aminobenzyl alcohol) have been synthesized and characterized by a number of techniques including X-ray photoelectron spectroscopy (XPS), 1H nuclear magnetic resonance spectroscopy (1H NMR), thermogravimetry (TG), differential scanning calorimetry (DSC), and ultraviolet-visible absorption spectroscopy (UV-vis). Conductivities of the HCl-doped polymer ranged from 101 S cm-l for polyaniline to 10-3 S cm-l for poly(o-aminobenzyl alcohol). Copolymer composition show that aniline and o-aminobenzyl alcohol have similar reactivities. The substituted polymers exhibited enhanced thermal stability and hydrogen-bonding interactions. The results were rationalized based on the effect of the -CH2OH substituent on the polymer structure.
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.contributor.departmentPHYSICS
dc.description.sourcetitleMacromolecules
dc.description.volume26
dc.description.issue1
dc.description.page144-150
dc.description.codenMAMOB
dc.identifier.isiutNOT_IN_WOS
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