Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2010.03.068
Title: Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates
Authors: White, B.C.
Harrison, D.
Henderson, W.
Nicholson, B.K.
Andy Hor, T.S. 
Keywords: Crystal structure
Electrospray mass spectrometry
Palladium complexes
Platinum complexes
Sulfido ligands
Trinuclear complexes
Issue Date: 10-Aug-2010
Citation: White, B.C., Harrison, D., Henderson, W., Nicholson, B.K., Andy Hor, T.S. (2010-08-10). Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates. Inorganica Chimica Acta 363 (11) : 2387-2393. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2010.03.068
Abstract: The reactions of [Pt2(μ-S)2(PPh3) 4] towards a range of palladium(II) complexes containing organometallic ligands (cyclopalladated N-donor ligands, η3- allyl, phenyl) have been explored, leading to the formation of a series of cationic, trinuclear sulfido-bridged aggregates containing {Pt 2PdS2} cores. [Pt2(μ-S)2(PPh 3)4] also reacts with the platinum(II) hydride complex trans-[PtHCl(PPh3)2] giving the adduct [Pt 2(μ-S)2(PPh3)4PtH(PPh 3)]+. X-ray crystal structure determinations on the complexes [Pt2(μ-S)2(PPh3) 4PdPh(PPh3)]PF6 and [Pt2(μ-S) 2(PPh3)4PtH(PPh3)]PF6 are reported, and show the expected bis μ3-sulfido aggregates with three square-planar metal centres. © 2010 Elsevier B.V. All rights reserved.
Source Title: Inorganica Chimica Acta
URI: http://scholarbank.nus.edu.sg/handle/10635/95027
ISSN: 00201693
DOI: 10.1016/j.ica.2010.03.068
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